Canna~Fangled Abstracts

Synthesis of (-)-Cannabimovone and Structural Reassignment of Anhydrocannabimovone through Gold(I)-Catalyzed Cycloisomerization.

By April 27, 2016No Comments
2016 Apr 27. doi: 10.1002/anie.201601834. [Epub ahead of print]

Abstract

PM 1aThe first total synthesis of cannabimovone from Cannabis sativa and anhydrocannabimovone was achieved by means of a highly stereoselective gold(I)-catalyzed cycloisomerization. The results led to reassignment of the structure of anhydrocannabimovone.
© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

KEYWORDS:

cannabinoids; cycloisomerization; gold; oxy-Michael reaction; total synthesis

PMID:
27119910
[PubMed – as supplied by publisher]
twin memes II